Avgas 100LL?
Generally on a car tuned to run the 100LL you assume the cats have been removed.
As a default, increasing the octane will not gain anything unless you are octane limited. You'd be better served by mixing some E85 in there, it's effectively about 105 octane, a slight blend to bring your tank to E25-30 is a similar boost in octane but often won't push the car lean enough to cause issues.
Are you just doing it for fun or is there a goal here?
As a default, increasing the octane will not gain anything unless you are octane limited. You'd be better served by mixing some E85 in there, it's effectively about 105 octane, a slight blend to bring your tank to E25-30 is a similar boost in octane but often won't push the car lean enough to cause issues.
Are you just doing it for fun or is there a goal here?
Generally on a car tuned to run the 100LL you assume the cats have been removed.
As a default, increasing the octane will not gain anything unless you are octane limited. You'd be better served by mixing some E85 in there, it's effectively about 105 octane, a slight blend to bring your tank to E25-30 is a similar boost in octane but often won't push the car lean enough to cause issues.
Are you just doing it for fun or is there a goal here?
As a default, increasing the octane will not gain anything unless you are octane limited. You'd be better served by mixing some E85 in there, it's effectively about 105 octane, a slight blend to bring your tank to E25-30 is a similar boost in octane but often won't push the car lean enough to cause issues.
Are you just doing it for fun or is there a goal here?
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There's much more to 100LL. It's aka 100/130.
At Lean A/F typical Octane is 99.6-102
At Rich A/F typical Octane is 130-132
Modern avgas is very different from 30 years earlier. Commonly held beliefs just ain't so.
The Tetraethyl-Lead density is currently limited at <0.56 g/l, but production avgas ranges from 0.36-0.50 g/l
Lead deposits in engines no longer exist, that was fixed decades ago. The TEL is reduced to Lead Oxide during combustion, this reaction increases Octane. They've added Ethylene Dibromide to scavenge Lead Oxide which forms Lead Bromide >>> Exhaust Gas. The lead oxide >> Ethylene Dibromide affinity is remarkably effective so Lead Oxide doesn't leave lead deposits behind. I've scoped and opened many engines and have never found visible lead deposits.
These engines are 550CI, Twin Turbo Charged, Twin Intercooled, Fuel injected, air cooled, 300HP at 2800 RPM continuous duty up to 25k AMSL and live 2000 Hours until OH.
The pilot has dash mounted controls for A/F ratio, Manifold Pressure, with Ex Gas Temps per cylinder displayed. The Pilot will tune A/F for peak power, then Lean Fuel known as Lean of Peak, for best economy, 100 Octane. Or the tune can be Rich of Peak where manifold pressure can be increased, utilizing 130 Octane.
Why it matters here... because those who play with 100LL avgas fully miss the point. Guys run 130 Race Gas at 3 ATM. That's not simple to do, but if you could just run avgas rich around 11:1 to allow +1 ATM boost, that'd be the bomb. Avgas power drop Rich of Peak is insignificant. Maybe add a big timing advance, 2x SC RPM, a load of Methanol and/or Water, lots of fun to be had.
At Lean A/F typical Octane is 99.6-102
At Rich A/F typical Octane is 130-132
Modern avgas is very different from 30 years earlier. Commonly held beliefs just ain't so.
The Tetraethyl-Lead density is currently limited at <0.56 g/l, but production avgas ranges from 0.36-0.50 g/l
Lead deposits in engines no longer exist, that was fixed decades ago. The TEL is reduced to Lead Oxide during combustion, this reaction increases Octane. They've added Ethylene Dibromide to scavenge Lead Oxide which forms Lead Bromide >>> Exhaust Gas. The lead oxide >> Ethylene Dibromide affinity is remarkably effective so Lead Oxide doesn't leave lead deposits behind. I've scoped and opened many engines and have never found visible lead deposits.
These engines are 550CI, Twin Turbo Charged, Twin Intercooled, Fuel injected, air cooled, 300HP at 2800 RPM continuous duty up to 25k AMSL and live 2000 Hours until OH.
The pilot has dash mounted controls for A/F ratio, Manifold Pressure, with Ex Gas Temps per cylinder displayed. The Pilot will tune A/F for peak power, then Lean Fuel known as Lean of Peak, for best economy, 100 Octane. Or the tune can be Rich of Peak where manifold pressure can be increased, utilizing 130 Octane.
Why it matters here... because those who play with 100LL avgas fully miss the point. Guys run 130 Race Gas at 3 ATM. That's not simple to do, but if you could just run avgas rich around 11:1 to allow +1 ATM boost, that'd be the bomb. Avgas power drop Rich of Peak is insignificant. Maybe add a big timing advance, 2x SC RPM, a load of Methanol and/or Water, lots of fun to be had.
Back when I raced, I watched people throw away money of high octane gas all the time. They would think higher octane meant better performance, but if the motor wasn't tuned to the high octane, it would run worse, and that was with unleaded. Add lead into the equation and the car would run horribly and you would have to buy a series of replacement parts that don't play well with lead.
Almost everyone clings to commonly held beliefs; most were true in the 60's or 70's.
I may not have clarified well. 100LL avgas has evolved substantially since long ago.
I shared the TEL density common now, I guess that was too obscure. TEL density is very low. More importantly decades ago, they added scavenging agents to carry the Lead-Oxide out with the exhaust.
In short, I doubt modern 100LL could lead foul anything when used for weekend drag fun. Many Aircraft piston engines have O2 sensors for Pilot information. That's the only fuel they use, and lead deposits have been effectively eliminated.
It's very true that Octane too high for the CC pressure will reduce engine power output below the correct Octane fuel. I could never feel the change, but a couple percent always shows up on finish line speed, and on the dyno. If you can add CC pressure, like with a waste gate, you'll get to burn more fuel; that's a great reason to increase Octane.
I've never seen this error break an engine, but it wouldn't surprise me.
I may not have clarified well. 100LL avgas has evolved substantially since long ago.
I shared the TEL density common now, I guess that was too obscure. TEL density is very low. More importantly decades ago, they added scavenging agents to carry the Lead-Oxide out with the exhaust.
In short, I doubt modern 100LL could lead foul anything when used for weekend drag fun. Many Aircraft piston engines have O2 sensors for Pilot information. That's the only fuel they use, and lead deposits have been effectively eliminated.
It's very true that Octane too high for the CC pressure will reduce engine power output below the correct Octane fuel. I could never feel the change, but a couple percent always shows up on finish line speed, and on the dyno. If you can add CC pressure, like with a waste gate, you'll get to burn more fuel; that's a great reason to increase Octane.
I've never seen this error break an engine, but it wouldn't surprise me.
your question is the opposite of stupid. It's stupid to pump avgas in to see what'll happen without at least asking.
I've watched mine hunt for most efficient ignition advance. It'll advance until knock is sensed, then retard just enough. It also hunts for leanest A/F limits. Very sophisticated controls. They do this to allow your trip to continue when the station has only 87 for sale. The range for these hunts probably does not extend up to 100 Octane, but I wish I knew.
I've watched mine hunt for most efficient ignition advance. It'll advance until knock is sensed, then retard just enough. It also hunts for leanest A/F limits. Very sophisticated controls. They do this to allow your trip to continue when the station has only 87 for sale. The range for these hunts probably does not extend up to 100 Octane, but I wish I knew.
The vast majority of general aviation planes do not have O2 sensors. There really isn't a need as you have manual control over so many more aspects of the engine. You spend time getting the engine leaned out just right for your altitude, curise speed (RPMs), etc. You don't have that in cars, where the computers rely on many things, including the O2 sensors. I personally have never flown a plane with O2 sensors as those were too new to be in my budget, so I can't speak from experience about the process for checking them and cleaning them. I do know that it's not the same as a car, though, and the O2 sensors in airplanes also have a much shorter lifespan and are designed for use with 100LL.
Last edited by eeeeek; May 15, 2026 at 11:01 AM.
O2 sensors don't control things, can be dash mounted dials, or just push data to a data storage, maybe now to an app.
Allowable TEL gets a fresh government reset when the producers lock chemist in a closet long enough to reduce. The produces report as required and have to serve up their secret sauce. The TEL is much lower, but more effective is the scavenging agents. There are a few, and the struggle continues. I've only seen a couple O2 reports. Guys with constant speed props and twin turbos think they are cheap. It'll identify one cylinder in-trouble during live operation, so that's cool. You could save an $90k engine, by finding the bad $8k Cylinder.
Whatever happens, or doesn't in an aircraft, will not likely repeat in an auto engine.
Allowable TEL gets a fresh government reset when the producers lock chemist in a closet long enough to reduce. The produces report as required and have to serve up their secret sauce. The TEL is much lower, but more effective is the scavenging agents. There are a few, and the struggle continues. I've only seen a couple O2 reports. Guys with constant speed props and twin turbos think they are cheap. It'll identify one cylinder in-trouble during live operation, so that's cool. You could save an $90k engine, by finding the bad $8k Cylinder.
Whatever happens, or doesn't in an aircraft, will not likely repeat in an auto engine.
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